Medical Chemistry • Test 1

Hydrocarbons & PAHs

10 Outcomes

1. Carbon Hybridisation & Bonds

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2. Structural & Skeletal Formulas

Compare IUPAC representations & isomer structures:

3. Families & IUPAC Quick Reference

Family Formula Suffix Key Feature
Alkanes CₙH₂ₙ₊₂ -ane Saturated, only σ bonds
Alkenes CₙH₂ₙ -ene C=C (1σ + 1π), cis/trans
Alkynes CₙH₂ₙ₋₂ -yne C≡C (1σ + 2π), linear
Arenes C₆H₆ (ring) -benzene Delocalised 6π e⁻ sextet
📌 Priority & Numbering Rule (IUPAC):

1. Longest carbon chain containing the principal unsaturated bond.
2. Number chain to give double/triple bonds the lowest locants before alkyl substituents.
3. Disubstituted benzene: 1,2- (ortho-), 1,3- (meta-), 1,4- (para-).